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Hg • Atomic Number 80

Mercury

Mercury is a white-silver, very dense metal and the only one that is liquid at room temperature. Its melting point is minus 39 degrees Celsius. The chemical symbol Hg comes from the Latin word hydrargyrum, meaning “liquid silver.”

Mercury forms amalgams or liquid alloys with copper, tin, and zinc. It has been used, for example, in dental fillings. Because mercury does not adhere to glass, it was traditionally used in thermometers.

Gold and silver dissolve easily in mercury, which is why it was historically used in the extraction of these precious metals.

The largest producer of mercury is China, followed by Tajikistan.

Due to its toxicity and environmental hazards, the use of mercury has sharply declined and is now limited to a few specialized applications.

The Minamata Convention, adopted in 2013, is an international treaty aimed at reducing mercury emissions and releases. To date, 148 of 193 countries have joined the agreement.

History

Mercury was already used in ancient Egypt and China as a pigment and in medicine — despite the fact that its toxicity was already known.

The Romans used mercury for gold extraction and began mining it in Almadén, Spain, as early as 400 BC. After the Romans, the Spanish exploited the Almadén mercury mine to extract gold in their South American colonies.

Around the year 1000, the palaces of the caliphs of Córdoba (Medina Azahara) in Spain featured fountains filled with mercury.

During the Middle Ages, alchemists believed that mercury was one of the key substances in the creation of gold. Medieval physicians experimented with mercury compounds to treat diseases such as syphilis — often with fatal consequences.

In 1643, the Italian physicist and mathematician Evangelista Torricelli developed the mercury barometer. Half a century later, in 1714, the German physicist Daniel Gabriel Fahrenheit built the mercury thermometer.

In the 19th century, mercury was widely used in North America for gold and silver extraction, leading to severe environmental contamination.

In the 20th century, mercury was used in the production of chlorine and sodium hydroxide.

Application

The good electrical conductivity of mercury makes it particularly useful for sealed electrical switches and relays. An electrical discharge through mercury vapor in a quartz glass tube or bulb produces a bluish glow with a high proportion of ultraviolet light. This phenomenon is utilized in ultraviolet, fluorescent, and high-pressure mercury vapor lamps. Today, mercury vapor lamps are used only in specialized lighting applications, such as film and stage lighting.

In some countries, traditional mercury thermometers and barometers are still in use; however, they are increasingly being replaced by digital or alcohol-based devices.

Mercury is also used in certain scientific instruments and experiments, for example in some spectrometers, in chemical research, and for military applications.

Amalgam dental fillings consist of 50 percent mercury, but have been banned in the EU since 2025.

Occurence, Mining and Extraction

The most important ore for mercury extraction is cinnabar.

China is the world’s largest producer of mercury, which is often obtained as a byproduct from gold and silver mines.

Recycling of batteries, fluorescent lamps, dental amalgam, medical devices, and thermostats also plays a role in mercury recovery.

The largest mercury mine in the world was located in Almadén, Spain, where the metal was mined for 2000 years until 2003.

Global annual production is estimated to exceed 1000 tons.

Substitution

Ceramic composites are replacing mercury-containing dental amalgam.

In mercury thermometers, Galinstan—an alloy of gallium, indium, and tin—has replaced mercury. Digital thermometers have taken the place of conventional ones.

In chlor-alkali plants worldwide, mercury cell technology is being replaced by newer diaphragm and membrane cell technologies.

Indium-based LEDs are replacing mercury-containing fluorescent lamps.

Lithium, nickel-cadmium, and zinc-air batteries have replaced mercury-zinc batteries.

Indium compounds are used instead of mercury in alkaline batteries, and organic compounds have replaced mercury-based fungicides in latex paints.