In • Atomic Number 49
Indium
Indium is a rare, silvery-white, and soft heavy metal. It is softer than lead and can be easily deformed. Like tin, the pure metal emits a high-pitched “scream” when bent.
Its abundance in the Earth's crust is comparable to that of silver.
It has the unusual property of adhering to and wetting clean glass and other surfaces in its molten state. This makes indium valuable for creating hermetic seals between glass, metals, quartz, ceramics, and marble.
The metal is frequently used in the manufacture of semiconductor devices. However, its most important application is in touchscreens, flat-panel displays (LCDs and OLEDs), and solar modules.
The element occurs in trace amounts in many minerals, especially those containing zinc and lead, from which it is extracted as a byproduct.
The main producing countries are China, South Korea, and Japan.
Key companies include Zhuzhou Smelter Group in China and Korea Zinc in South Korea.
Indium was discovered in 1863 by the German chemists Ferdinand Reich and Hieronymus Theodor Richter during the analysis of zinc ore samples. The presence of a prominent indigo-blue spectral line inspired the name.
A larger quantity of indium was first exhibited at the 1867 World’s Fair in Paris.
After an initial application starting in 1933 as an alloy component in dental gold, the extensive use of indium began with World War II. The United States used it as a coating in heavily stressed aircraft bearings.
After World War II, indium was primarily employed in the electronics industry, as solder material, and in low-melting alloys. Its use in control rods for nuclear reactors also became important with the increasing adoption of nuclear energy. This led to a first significant rise in the price of indium by 1980.
Starting in 1987, two new indium compounds were developed: the semiconductor indium phosphide and indium tin oxide, which is conductive and transparent in thin layers. Indium tin oxide became particularly important with the development of liquid crystal displays. Due to high demand, since 1992 the majority of indium has been further processed into indium tin oxide.
Indium is mainly used as indium tin oxide (ITO), a transparent, conductive coating essential for touchscreens, flat-panel displays (LCDs and OLEDs), and solar modules. About three-quarters of the demand for indium comes from touchscreens, LCD and OLED monitors, and foldable displays.
Ten to fifteen percent is used in the manufacture of solar cells (thin-film solar cells, perovskite solar cells).
Indium also plays a role in nuclear reactors.
The worldwide indium production amounts to approximately 1.000 tons annually.
Indium is a byproduct of zinc mining (about 1 ton of indium per 1.000 tons of zinc). Ninety percent of global production is extracted from the zinc ore sphalerite.
China, Canada, and Peru have zinc deposits with significant indium content, with China dominating the global indium production market with a share of over 50 percent. The largest indium company is Zhuzhou Smelter Group.
About 30 percent of indium now comes from recycling.
Antimony tin oxide coatings have been developed as an alternative to ITO coatings in LCDs.
Carbon nanotube coatings have been developed as an alternative to ITO coatings in flexible displays, solar cells, and touchscreens.
Poly(3,4-ethylenedioxythiophene) (PEDOT) has also been developed as a replacement for ITO in flexible displays and organic light-emitting diodes (OLEDs). Copper or silver nanowires have been investigated as substitutes for ITO in touchscreens.
Graphene has been developed as a replacement for ITO electrodes in solar cells and has also been studied as a substitute for ITO in flexible touchscreens.
Hafnium can replace indium in control rod alloys for nuclear reactors.
Critical and Strategic Metals